Journal article
Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers.
- Le Vaillant F Laboratory of Catalysis and Organic Synthesis , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland . Email: jerome.waser@epfl.ch.
- Garreau M Laboratory of Catalysis and Organic Synthesis , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland . Email: jerome.waser@epfl.ch.
- Nicolai S Laboratory of Catalysis and Organic Synthesis , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland . Email: jerome.waser@epfl.ch.
- Gryn'ova G Laboratory for Computational Molecular Design , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland.
- Corminboeuf C Laboratory for Computational Molecular Design , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland.
- Waser J Laboratory of Catalysis and Organic Synthesis , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland . Email: jerome.waser@epfl.ch.
- 2018-08-07
Published in:
- Chemical science. - 2018
English
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers. The redox properties of the dyes were determined by both cyclic voltammetry and computation and covered an existing gap in the oxidation potential of photoredox organocatalysts.
- Language
-
- English
- Open access status
- gold
- Identifiers
-
- DOI 10.1039/c8sc01818a
- PMID 30079201
- Persistent URL
- https://sonar.rero.ch/global/documents/151155
Statistics
Document views: 19
File downloads: